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  1. Markovnikov's rule - Wikipedia

    In organic chemistry, Markovnikov's rule or Markownikoff's rule describes the outcome of some addition reactions. The rule was formulated by Russian chemist Vladimir Markovnikov in 1870. …

  2. Markovnikov’s Rule - Chemistry LibreTexts

    Markovnikov’s rule is an empirical rule used to predict regioselectivity of electrophilic addition reactions of alkenes and alkynes. It states that, in hydrohalogenation of an unsymmetrical …

  3. Hydrohalogenation of Alkenes and Markovnikov's Rule – Master …

    Feb 8, 2013 · The reaction tends to occur such that the halogen ends up attached to the carbon of the alkene attached to the fewest hydrogen atoms, a phenomenon known as Markovnikov’s Rule.

  4. Markovnikov rule | Addition of Hydrogen, Alkenes, Alkanes

    Markovnikov rule, in organic chemistry, a generalization, formulated by Vladimir Vasilyevich Markovnikov in 1869, stating that in addition reactions to unsymmetrical alkenes, the electron …

  5. Markovnikov’s Rule with Practice Problems - Chemistry Steps

    This preference for addition to alkenes was first explained by Markovnikov and is known as Markovnikov’s rule which states that: In the addition reaction of HX to an unsymmetrical …

  6. Markovnikov's Rule - Organic Chemistry Portal

    Markovnikov Rule predicts the regiochemistry of HX addition to unsymmetrically substituted alkenes. The halide component of HX bonds preferentially at the more highly substituted …

  7. 7.8 Orientation of Electrophilic Additions: Markovnikov’s Rule ...

    After looking at the results of many such reactions, the Russian chemist Vladimir Markovnikov proposed in 1869 what has become known as: In the addition of HX to an alkene, the H …

  8. Markovnikov Rule - GeeksforGeeks

    Jul 23, 2025 · Markovnikov's Rule is a principle in organic chemistry that helps predict the outcome of an addition reaction when an unsymmetrical molecule reacts with a molecule …

  9. Markovnikov’s Rule - ChemTalk

    Markovnikov’s rule helps predict the product of nucleophilic addition to alkenes. The nucleophile adds to the carbon with the highest degree (primary, secondary, etc.).

  10. Markovnikov's Rule Definition, Explanation of Mechanism with …

    What is Markovnikov's Rule definition, explanation, Anti-Markovnikov's Rule mechanism, examples and pictures